Enzymatic transesterification of Jatropha oil
نویسندگان
چکیده
BACKGROUND Transesterification of Jatropha oil was carried out in t-butanol solvent using immobilized lipase from Enterobacter aerogenes. The presence of t-butanol significantly reduced the negative effects caused by both methanol and glycerol. The effects of various reaction parameters on transesterification of Jatropha oil were studied. RESULTS The maximum yield of biodiesel was 94% (of which 68% conversion was achieved with respect to methyl oleate) with an oil:methanol molar ratio of 1:4, 50 U of immobilized lipase/g of oil, and a t-butanol:oil volume ratio of 0.8:1 at 55 degrees C after 48 h of reaction time. There was negligible loss in lipase activity even after repeated use for seven cycles. CONCLUSION To the best of our knowledge this is the first report on biodiesel synthesis using immobilized E. aerogenes lipase.
منابع مشابه
Lipase-catalyzed biodiesel production and quality with Jatropha curcas oil: exploring its potential for Central America
BACKGROUND Extensive native Jatropha curcas L. (Jatropha) crop areas have been planted in Central America marginal lands since 2008 as a non-edible prospective feedstock alternative to high-value, edible palm oil. Jatropha biodiesel is currently exclusively produced in the region at commercial scale utilizing alkaline catalysts. Recently, a free, soluble Thermomyces lanuginosus (TL) 1,3 specifi...
متن کاملCOMPARATIVE STUDY OF ENZYMATIC TRANSESTERIFICATION OF Jatropha OIL USING LIPASE FROM Jatropha curcas and Jatropha gossipyfolia
Biodiesel consists of monoalkyl esters of long chain fatty acids. It is produced from vegetable oils or fats either by chemical transesterification with methanol or ethanol. The cost of lipases and the relatively slower reaction rate remain as the major obstacles for enzymatic production of biodiesel as opposed to the conventional chemical processes. The enzymatic process offers several advanta...
متن کاملProduction of biodiesel from non-edible Jatropha curcas oil via transesterification using Bi2O3-La2O3 catalyst ABSTRACT The simultaneous esterification and transesterification of Jatropha curcas
The simultaneous esterification and transesterification of Jatropha curcas oil (JCO) was carried out in the presence of Bi2O3 (1–7 wt.%) modified La2O3 catalyst at atmospheric pressure. The catalyst were characterized by X-ray diffraction (XRD), BET surface area, desorption of CO2 (TPD-CO2) and NH3 (TPD-NH3). Under the optimal reaction condition of methanol/oil molar ratio of 15:1, 2 wt.% of ca...
متن کاملSelection of Lipases for the Synthesis of Biodiesel from Jatropha Oil and the Potential of Microwave Irradiation to Enhance the Reaction Rate
The present study deals with the enzymatic synthesis of biodiesel by transesterification of Jatropha oil (Jatropha curcas L.) with ethanol in a solvent-free system. Seven commercial lipase preparations immobilized by covalent attachment on epoxy-polysiloxane-polyvinyl alcohol composite (epoxy-SiO2-PVA) were tested as biocatalysts. Among them, immobilized lipases from Pseudomonas fluorescens (li...
متن کاملProducing Biodiesel from High Free Fatty Acid Jatropha Curcas Oil by A Two Step Method- An Indian Case Study
Being an agricultural product, the properties of crude Jatropha Curcas oil (CJCO) and the biodiesel produced from CJCO are region specific. In this work studies were carried out to produce biodiesel from crude Jatropha Curcas oil with a having high free fatty acid contents (6.85%) obtained from rural areas within India. Due its high free fatty acid content, the crude Jatropha Curcas oil was pro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Biotechnology for Biofuels
دوره 2 شماره
صفحات -
تاریخ انتشار 2009